d-f跃迁发光稀土配合物研究进展

稀土配合物独特的发光性质使其在众多领域有很大的应用价值。其中, d-f跃迁发光稀土配合物具有跃迁宇称允许、激发态寿命短和光谱可调等特点,但相关研究还有待进一步深入。本文介绍了稀土配合物的发光机制,综述了具有d-f跃迁发光性质的稀土配合物(主要是Ce³⁺, Eu²⁺, Yb²⁺和Sm²⁺配合物)的研究进展,并初步总结了配合物分子结构对d-f跃迁发光性质的影响规律。     

飞行试验大数据技术及展望

现代航空武器装备综合化和信息化程度越来越高,飞行试验测试数据的种类增多,测试数据量剧增,飞行试验进入了大数据时代。试飞大数据的来临,对试验数据的获取、记录、传输和处理等传统技术及模式产生了强大的冲击,也提出了严峻的挑战。本文在简要介绍大数据概念及国外研究应用现状的基础上,通过总结分析飞行试验数据的新特征、新需求,提出了“试飞大数据”的概念,得出飞行试验数据是典型大数据的结论;按照试飞测试流程和大数据技术范畴,重点分析了试飞大数据技术中的数据获取、交换、记录、传输、监控、处理、存储等关键技术,最后,对试飞大数据技术的应用前景进行了展望。     

Characterization of Cr‐doped Sb2Te3 films and their application to phase‐change memory

Phase‐change memory (PCM) is regarded as one of the most promising candidates for the next‐generation nonvolatile memory. Its storage medium, phase‐change material, has attracted continuous exploration. Along the traditional GeTe–Sb₂Te₃ tie line, the binary compound Sb₂Te₃ is a high‐speed phase‐change material matrix. However, the low crystallization temperature prevents its practical application in PCM. Here, Cr is doped into Sb₂Te₃, called Cr–Sb₂Te₃ (CST), to improve the thermal stability. We find that, with increase of the Cr concentration, grains are obviously refined. However, all the CST films exhibit a single hexagonal phase as Sb₂Te₃ without phase separation. Also, the Cr helps to inhibit oxidation of Sb atoms. For the selected film CST_10.5, the resistance ratio between amorphous and crystalline states is more than two orders of magnitude; the temperature for 10‐year data retention is 120.8 °C, which indicates better thermal stability than GST and pure Sb₂Te₃. PCM cells based on CST_10.5 present small threshold current/voltage (4 μA/0.67 V). In addition, the cell can be operated by a low SET/RESET voltage pulse (1.1 V/2.4 V) with 50 ns width. Thus, Cr–Sb₂Te₃ with suitable composition is a promising novel phase‐change material used for PCM with high speed and good thermal stability performances. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

Auto‐Oxidative Coupling of Glycine Derivatives

The unprecedented title reaction between glycine derivatives and indoles, as well as the auto‐oxidative Povarov/aromatization tandem reaction of glycine derivatives with olefins are described. The reactions were performed in the absence of redox‐active catalysts and chemical oxidants under mild reaction conditions. Only simple organic solvents and air (or O₂) were required.     

A pyridoxal-based chemosensor for visual detection of copper ion and its application in bioimaging

A pyridoxal-based chemosensor was synthesized by reacting hydrazine hydrate and pyridoxal hydrochloride in ethanol and characterized by NMR and ESI-MS.The optical properties of the compound were investigated in a methanol:HEPES solution.The compound displayed selectivity for Cu2+,as evidenced by a colorless to yellow color change,which was characterized using UV–vis spectroscopy.The fluorescence of the compound can be quenched only by Cu2+,accompanying by a color change from blue to colorless.Furthermore,it can be used in bioimaging.     

Interfacial Strain Release from the WS2/CsPbBr3 van der Waals Heterostructure for 1.7 V Voltage All-Inorganic Perovskite Solar Cells

Perovskite lattice distortion induced by residual tensile strain from the thermal expansion mismatch between the electron-transporting layer (ETL) and perovskite film causes a sluggish charge extraction and transfer dynamics in all-inorganic CsPbBr₃ perovskite solar cells (PSCs) because of their higher crystallization temperatures and thermal expansion coefficients. Herein, the interfacial strain is released by fabricating a WS₂/CsPbBr₃ van der Waals heterostructure owing to their matched crystal lattice structure and the atomically smooth dangling bond-free surface to act as a lubricant between ETL and CsPbBr₃ perovskite. Arising from the strain-released interface and condensed perovskite lattice, the best device achieves an efficiency of 10.65 % with an ultrahigh open-circuit voltage of 1.70 V and significantly improved stability under persistent light irradiation and humidity (80 %) attack over 120 days.     

Two-Coordinate Copper(I)/NHC Complexes: Dual Emission Properties and Ultralong Room-Temperature Phosphorescence

As a kind of photoluminescent material, Cu^I complexes have many advantages such as adjustable emission, variable structures, and low cost, attracting attention in many fields. In this work, two novel two-coordinate Cu^I-N-heterocyclic carbene complexes were synthesized, and they exhibit unique dual emission properties, fluorescence and phosphorescence. The crystal structure, packing mode, and photophysical properties under different conditions were systematically studied, proving the emissive mechanism to be the locally excited state of the carbazole group. Based on this mechanism, ultralong room-temperature phosphorescence (RTP) with a lifetime of 140 ms is achieved by selective deuteration of the carbazole group. These results deepen the understanding of the luminescence mechanism and design strategy for two-coordinate Cu^I complexes, and prove their potential in applications as ultralong RTP materials.     

Oxidative Dehydrogenative Silylation‐Alkenation Reaction of Alkyl Aromatics with Silanes

A Cu(OAc)₂/DDQ/DTBP/Py system catalyzed oxidative dehydrogenative silylation‐alkenation tandem reaction of readily available alkyl aromatic compounds with silanes was established. A variety of functionalized alkenyl organosilicon compounds were provided in good to high yields with a total β‐(E) selectivity. The control experiments revealed that the transformation might proceed through a radical pathway.     

Metal–Organic Frameworks as Metal Ion Precursors for the Synthesis of Nanocomposites for Lithium‐Ion Batteries

Metal–organic frameworks (MOFs) are promising materials with fascinating properties. Their widespread applications are sometimes hindered by the intrinsic instability of frameworks. However, this instability of MOFs can also be exploited for useful purposes. Herein, we report the use of MOFs as metal ion precursors for constructing functional nanocomposites by utilizing the instability of MOFs. The heterogeneous growth process of nanostructures on substrates involves the release of metal ions, nucleation on substrates, and formation of a covering structure. Specifically, the synthesized CoS with carbon nanotubes as substrates display enhanced performance in a lithium‐ion battery. Such strategy not only presents a new way for exploiting the instability of MOFs but also supplies a prospect for designing versatile functional nanocomposites.     

Fluevirines E and F,two new alkaloids from Flueggea virosa

Abstract

Two new alkaloids, fluevirines E (1) and F (2), along with six known Securinega alkaloids, were isolated from the methanol extract of the twigs and leaves of Flueggea virosa. The structures and absolute configurations of the new compounds were elucidated by means of MS, NMR, and ECD analyses. Compound 1 is a new dimeric indole alkaloid while 2 is a new securinega-type alkaloid. The in vitro cytotoxic activities of the isolated alkaloids against several human cancer cell lines and their acetylcholinesterase inhibitory activity were also evaluated.